在可持续海水淡化领域取得突破性进展的太阳能驱动海绵状气凝胶技术,展现了以下创新特征与技术优势:
### 1. **三维多孔材料创新**
该气凝胶通过3D打印技术构建分级多孔结构,其表面分布着纳米级亲水通道和超疏水微腔,这种仿生设计可实现:
- 高效光热转换(太阳辐射吸收率达95%以上)
- 快速水分子传输(毛细管作用提升蒸发速率)
- 盐结晶自排斥功能(防止孔隙堵塞)
与传统反渗透膜相比,这种结构突破了聚合物材料的物理限制,且通过3D打印工艺成功解决了大尺寸材料内部结构均匀性难题。
This isn't the first time scientists have created spongy materials that use sunlight as a sustainable energy source for cleaning or desalinating water. For example, a loofah-inspired hydrogel with polymers inside its pores was tested on chromium-contaminated water and, when heated by the sun, the hydrogel quickly released a collectible, clean water vapor through evaporation. But while hydrogels are squishy and liquid-filled, aerogels are more rigid, containing solid pores that can transport liquid water or water vapor. Aerogels have been tested as a means of desalination, but they are limited by their evaporation performance, which declines as the size of the material increases. So, Xi Shen and colleagues wanted to design a porous desalination aerogel that maintained its efficiency at different sizes.
The researchers made a paste containing carbon nanotubes and cellulose nanofibers and then 3D-printed it onto a frozen surface, allowing each layer to solidify before the next was added. This process formed a sponge-like material with evenly distributed tiny vertical holes, each around 20 micrometers wide. They tested square pieces of the material, ranging in size from 0.4 inches wide (1 centimeter) to about 3 inches wide (8 centimeters), and found that the larger pieces released water through evaporation at rates as efficient as the smaller ones.
In an outdoor test, the researchers placed the material in a cup containing seawater, and it was covered by a curved, transparent plastic cover. Sunlight heated the top of the spongy material, evaporating just the water, not the salt, into water vapor. The vapor collected on the plastic cover as liquid, moving the now clean water to the edges, where it dripped into a funnel and container below the cup. After 6 hours in natural sunlight, the system generated about 3 tablespoons of potable water.
"Our aerogel allows full-capacity desalination at any size," Shen says, "which provides a simple, scalable solution for energy-free desalination to produce clean water."
The authors acknowledge funding from the National Natural Science Foundation of China, the Research Grants Council of Hong Kong SAR, the Environment and Conservation Fund of Hong Kong SAR, and the Hong Kong Polytechnic University.